Single-molecule magnet behaviour in polynuclear assembly of trivalent Cerium ions with Polymolybdates

Abstract : An isopolyoxomolybdate-based POM is coordinated to trivalent cerium ions to afford a hybrid complex namely, [Ce(dmso)8][Ce([small eta]2-NO3)2(dmso)4([small alpha]-Mo8O26)0.5][Mo6O19]. The original electrostatic environment created around the CeIII by its coordination to the isopolyoxomolybdate core induces complex single-molecule magnet behavior.
Document type :
Journal articles
Complete list of metadatas

https://hal-insa-rennes.archives-ouvertes.fr/hal-01201884
Contributor : Isabelle Morlais <>
Submitted on : Friday, September 18, 2015 - 11:51:56 AM
Last modification on : Thursday, February 7, 2019 - 2:52:44 PM

Links full text

Identifiers

Citation

Arbia Ben Khélifa, M. Salah Belkhiria, Gang Huang, Stéphane Freslon, Olivier Guillou, et al.. Single-molecule magnet behaviour in polynuclear assembly of trivalent Cerium ions with Polymolybdates. Dalton Transactions, Royal Society of Chemistry, 2015, 44 (37), pp.16458-16464. ⟨10.1039/c5dt02377g⟩. ⟨hal-01201884⟩

Share

Metrics

Record views

225