Single-molecule magnet behaviour in polynuclear assembly of trivalent Cerium ions with Polymolybdates - Archive ouverte HAL Access content directly
Journal Articles Dalton Transactions Year : 2015

Single-molecule magnet behaviour in polynuclear assembly of trivalent Cerium ions with Polymolybdates

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Abstract

An isopolyoxomolybdate-based POM is coordinated to trivalent cerium ions to afford a hybrid complex namely, [Ce(dmso)8][Ce(η2-NO3)2(dmso)4(α-Mo8O26)0.5][Mo6O19]. The original electrostatic environment created around the Ce(III) by its coordination to the isopolyoxomolybdate core induces complex single-molecule magnet behavior.
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hal-01201884 , version 1 (18-09-2015)

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Arbia Ben Khélifa, M. Salah Belkhiria, Gang Huang, Stéphane Freslon, Olivier Guillou, et al.. Single-molecule magnet behaviour in polynuclear assembly of trivalent Cerium ions with Polymolybdates. Dalton Transactions, 2015, 44 (37), pp.16458-16464. ⟨10.1039/c5dt02377g⟩. ⟨hal-01201884⟩
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